Advances in molecular electrochemical activation of dinitrogen

Nitrogen fixation is an important and challenging transformation in chemistry. It currently achieved by the Haber–Bosch process that reduces N2 to NH3 on large scale but at cost of a huge environmental footprint. In search for greener processes, electrochemically driven reduction might become sustainable answer. The development molecular homogeneous catalysis has gained momentum over last decades, we focus this review emerging electrochemical systems based catalysts fixation.